2-[(2,6-Diisopropylphenyl)iminomethyl]-4-iodophenol
نویسندگان
چکیده
The asymmetric unit of title compound, C(19)H(22)INO, contains two independent mol-ecules. Classical intra-molecular O-H⋯N hydrogen bonds stabilize the mol-ecular structures. The crystal structure is stabilized by weak inter-molecular C-H⋯π and π-π [centroid-centroid = 3.8622 (18) Å] inter-actions. In both mol-ecules, the aromatic rings are nearly perpendicular to each other [dihedral angles = 84.26 (17) and 86.69 (15)°].
منابع مشابه
Di-μ-chlorido-bis({9-[(2,6-diisopropylphenyl)iminomethyl]anthracen-1-yl}palladium(II))
The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.
متن کامل2-Bromo-4-chloro-6-[(2,6-diisopropylphenyl)iminomethyl]phenol
There are two molecules in the asymmetric unit of the title compound, C(19)H(21)BrClNO, with dihedral angles between the aromatic rings of 70.0 (2) and 81.9 (3)°. The crystal structure is stabilized by inter-molecular C-H⋯π and C-Br⋯π inter-actions. In additional, the stacked mol-ecules exhibit intra-molecular O-H⋯N hydrogen bonds.
متن کامل4-Chloro-2-[(2,6-diisopropylphenyl)iminomethyl]phenol
The asymmetric unit of the title compound, C(19)H(22)ClNO, contains two independent mol-ecules in which the dihedral angles between the aromatic rings are 76.45 (9) and 74.69 (9)°. An intra-molecular O-H⋯N hydrogen bond occurs in each mol-ecule. The crystal structure features weak C-H⋯π inter-actions.
متن کاملTetraaquabis{μ2-2,7-bis[(2,6-diisopropylphenyl)iminomethyl]naphthalene-1,8-diolato}di-μ3-hydroxido-di-μ2-hydroxido-bis(trimethylphosphine oxide)tetranickel(II)–trimethylphosphine oxide–diethyl ether–water (1/2/2/2)
The title complex, [Ni(4)(C(36)H(40)N(2)O(2))(2)(OH)(4)(C(3)H(9)OP)(2)(H(2)O)(4)]·2C(4)H(10)O·2C(3)H(9)OP·2H(2)O, is centrosymmetric with a central core that can be described as a defect double cubane. The four metal ions in the cluster are held together by four bridging hydroxide groups. Each Ni(II) atom adopts a distorted octa-hedral geometry.
متن کامل(E)-4-Bromo-2-[(2,6-diisopropylphenyl)iminomethyl]phenol
In the title compound, C(19)H(22)BrNO, the dihedral angle between the benzene rings is 76.17 (14)° and an intra-molecular O-H⋯N hydrogen bond with an S(6) graph-set motif is present. One methyl group is disordered over two sets of sites with site occupancies of 0.66 (3) and 0.34 (3). A weak inter-molecular C-H⋯π inter-action is observed in the crystal structure.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012